• 专利附录
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    • 专利摘要:
    Composition to mineralize gases of carbon dioxide and nitrogen oxide that comprises a mixture of magnesium (between 1 and 25%), iron (between 1 and 23%), calcium monoxide (between 1 and 25%)), titanium dioxide (between 0.1 and 11%) and silicon dioxide (between 16 and 75%), with a particle diameter between 100 nm and 4000 μm. It produces the mineralization of carbon dioxide (CO2) and gaseous chemical compounds known as "nitrogen oxides" (NOx) in the atmosphere. This composition can be added or mixed as an additive in paints, dyes, resins and elastic polymers (rubber and rubber) in wearing parts, and for all types of coatings. (Machine-translation by Google Translate, not legally binding)
    公开号:ES2681120A1
    申请号:ES201730156
    申请日:2017-02-09
    公开日:2018-09-11
    发明作者:José Antonio SIVERA MARZA；Juan Carlos LLOBREGAT AGUSTÍ
    申请人:Primlab Global SL；
    IPC主号:
    专利说明:

    COMPOSITION TO MINERALIZE CARBON DIOXIDE GASES ANDNITROGEN OXIDE AND USES OF THE SAME OBJECT OF THE INVENTION
    The object of the invention is the mineralization of carbon dioxide (CO2) and gaseous chemical compounds known as "nitrogen oxides" (NOx)
    10 anthropogenic in the atmosphere, which allows to capture and undo these harmful gases to reduce the increase of the greenhouse effect and its consequences on health.
    This composition allows both the individual and collective level to eliminate the
    15 CO2 and atmospheric NOx, contributing to reduce the impact derived from these gases. For this purpose, a specific formulation is made with components that mineralize, absorb / adsorb CO2 and NOx, turning them into a white calcareous powder. These components can be added or mixed in paints, dyes, resins and elastic polymers (rubber and rubber) or for all types of coatings.
    The present invention is intended to control pollution and the industrial sectors of paints, dyes, resins and rubber and rubber products. BACKGROUND OF THE INVENTION
    25 Climate change is the greatest environmental threat of the 21st century, with major economic, health and environmental consequences. All without exception: citizens, businesses, economies and nature throughout the world are being affected. The lethal effects of high concentrations of CO2 and NOx are good
    30 known, but the anthropogenic levels of such gases are of concern both for survivors of high-level exposure of CO2 and NOx and for individuals experiencing prolonged low-level exposure.
    When looking for the cause of this acceleration it has been possible to demonstrate that there is a direct relationship between global warming or climate change and the increase in emissions


    of greenhouse gases, such as carbon dioxide (CO2), methane (CH4), water vapor, nitrous oxide (NO2), hydrofluorocarbons (HFC) or perfluorocarbons (PFC) and sulfur hexafluoride (SF6), caused by human societies (anthropic) both developed and developing (5 industrialization based on fossil fuels and / or other chemical components). The level of CO2 emissions has increased by 31%; methane (CH4) has been increased by 145% and nitrogen oxides (NOx = NO + NO2) by 15%. CO2 and NOx are of great relevance in urban centers due to their degree of contamination. It is known that CO2 concentrations in the atmosphere currently exceed
    10 reached in the last half million years, and probably in the last 20 million years, currently exceeding 400 ppm (according to the United States National Oceanic and Atmospheric Administration - NOAA) (Pieter Tans, 2016 ) and the tendency is that this acceleration will be exponential if no measures are taken to control it.
    15 CO2 is a primary pollutant. Given its natural presence in the atmosphere and its lack of toxicity, it should not be considered a substance that pollutes, but there are two circumstances that make it a pollutant of great importance today: it is a gas that produces an important effect of entrapment of the heat, the call
    20 greenhouse effect, and its concentration is increasing in recent years by the burning of fossil fuels and large areas of forest.
    Nitrogen oxides are a group of gases composed of nitric oxide (NO) and nitrogen dioxide (NO2). The term NOX refers to the combination of both substances.
    Nitrogen dioxide is the main pollutant within nitrogen oxides, and is formed as a byproduct in all combustions carried out at high temperatures. It is a yellowish substance, which is formed in the 30 combustion processes in motor vehicles and power plants. It is a toxic gas, irritant and precursor of nitrate particle formation, which leads to the production of acids and high levels of suspended particles (PM) of 2.5 microns in the environment. It has good solubility in water, reacting and forming nitric acid (HNO3) according to the following reaction: NO2 + H2O -> 2 HNO3 + NO. This substance is a strong oxidant and reacts violently with combustible materials.


    and reducers, being able to attack metallic materials in the presence of water.
    The effects of CO2 on a specific individual depend on the concentration andduration of exposure, as well as individual factors, such as age, health,5 physiological composition, physical activity, occupation and lifestyle. The exhibitionconstant (high or low) to CO2 and NOx can cause significant adverse effects ofpersistent health, such as headaches, attacks of vertigo, lack of memory andability to concentrate, difficulty sleeping, tinnitus, double vision, photophobia,loss of eye movement, visual field defects, enlargement of
    10 blind spots, poor adaptation to darkness, respiratory or cancerous problems and personality changes, among other health problems.
    Likewise, the phenomenon called acid rain also occurs. NOx, due to ambient humidity and solar ultraviolet radiation, react with radicals
    15 hydroxyls to form nitric acid that together with the sulfurous and sulfuric acids that form from SO2 modify the pH of the water and form the so-called acid precipitations.
    There are different, very expensive and economically unfeasible methods of reducing the level of CO2, such as CO2 sequestration when injected directly into the depths of the oceans.
    The effects on human health and the environment of NO2 are well known. It is a corrosive substance for the skin and respiratory tract, causing redness and severe skin burns. Inhalation at high concentrations and for a short period of time can cause pulmonary edema whose effects are not observed until after a few hours, worsening with physical exertion. Prolonged exposure may affect the immune system and lung, resulting in reduced resistance to infections and causing changes.
    30 irreversible in lung tissue.
    The large-scale use of titanium dioxide coatings is of special interest, because their photocatalytic effect causes the disintegration of harmful substances in the air. This disintegration has long been known as an efficient method for transmutation of harmful substances into


    harmless products, through solar energy, which is based on the ability to capture free radicals generated by the absorption of light on the semiconductor surface and use them for electron transfer reactions.
    5 There are currently products on the market, such as photocatalytic paints, that carry titanium dioxide to neutralize NOx, as demonstrated in patent PCT / US2008 / 074876 (whose description is incorporated by reference), other products that absorb CO2 ( such as cements and paints) and various techniques to sequester such harmful gases. The main problems that these products have are that
    10 photocatalytic paints with titanium dioxide transform NOx by generating CO2 and H2O as a byproduct and increase CO2 levels. Paints whose composition is based on Ca (OH) 2, calcium hydroxide, to absorb CO2 have the disadvantage that they are simply absorbing CO2 and increasing the weight of the surface where they are applied. EXPLANATION OF THE INVENTION
    The present invention has the direct purpose of mineralizing CO2 carbon dioxide and NOx nitrogen oxides with a single mineral composition to reduce its environmental impact and reduce risks to human health. The main inorganic materials of our composition are preferably from igneous rocks, sedimentary and metamorphic rocks (magnesium, iron, calcium monoxide, silicon dioxide, titanium oxide (IV)), the latter used as a photocatalyst. They are mixed in the manufacture of paints, dyes and materials of
    25 rubber / rubber between a percentage of 0.5% to 15% by weight and with a particle diameter between 100 nm and 4000 µm, for example measured by filtration with laboratory sieves. Paints and / or dyes are applied directly to surfaces in different ways, such as walls, floors, all kinds of road signs, vehicles, textiles, plastic compounds etc.
    30 Adsorption is a process by which atoms, ions or molecules are trapped or retained on the surface of a material, acting as a molecular sieve. Absorption is a physical process of a solid substance or a liquid that attracts or retains respectively, a liquid, a gas or vapor.


    The mode of action of the paint, rubber / rubber with our formulation is by the process of carbonation and nitrification at room temperature. When they come into contact with CO2 or environmental NOx they have an absorption / adsorption power, through the mentioned processes, they chemically trap the particles of said
    5 gases converting them into biproducts (white calcareous powder). CO2 and NOx become these biproducts and get trapped on the surface, so they disperse to the ground through rains or environmental elements (wind, rain, snowfall, etc.), these biproducts are beneficial for the environment and are not harmful to health.
    10 Our composition, once applied to the various materials mentioned above, when it comes into contact with carbon oxides and nitrogen oxides begins a carbonation and nitrification process by which it absorbs / adsorbs and transforms CO2 and NOx. The reaction of these minerals in the present invention
    15 (MgFeCaOTiO2) + SiO2 + 3CO2 = MgCO3 + FeCO3 + CaCO3 + TiO + SiO. The composition is rich in Mg (between 1 and 25% by weight), Fe (between 1 and 23%), CaO (between 1 and 25%), TiO2 (between 0.1 and 11 %) and SiO2 (between 16 and 75%) make the natural process of absorption / adsorption and transformation of CO2. Titanium (IV) oxide (TiO2) is a photocatalyst that uses sunlight or artificial light to
    20 absorb nitrogen oxides (NO and NO2) and transform them into harmless nitrates (NO +
    O2 → NO3, NO2 + OH → H ++ NO3).
    The reaction between our composition and CO2 can be simplified as two processes that take place at the same time: Mg / Fe / CaO / TiO2 + 4CO2 → MgCO3,
    25 FeCO3, CaCO3, TiO2 (conversion into powder of magnetite, siderite, limestone and titanium dioxide (IV)) which acts as a catalyst by light for the nitrification of NOx and Si (O2) → SiO2 (conversion of cristobalite quartz equivalent). The first is the production of carbonate minerals, which sequesters CO2. The second is the conversion of cristobalite to quartz.
    30 The durability of our composition depends on the area in which the product is exposed, that is, as long as there are minerals left in the applied product there will be carbonation and nitrification. There are parts on the planet that exceed 400 ppm of CO2 in the air, while others have lower levels, as is the case with
    35 concentrations of NOx. The paintings remain active between 7 and 10 years


    approximately, depending on the atmospheric conditions, this is the durability of the composition and the rubber or rubber products, depending on its use, such as a wheel of a vehicle, is due to tire wear. In rubber or rubber elements, since rubber and rubber are not porous,
    5 only the outer part is effective. However, in the case of tires, the composition part that is in contact with the air is being renewed as the vehicle wears out the wheels. Therefore, the invention is preferred to the use of the composition in rubber or rubber wear elements, since otherwise the efficiency is reduced.
    10 Our composition is made with igneous rocks, although it can also be manufactured chemically, but this process is more expensive and would increase the carbon footprint by its production. With this composition, in addition to removing NOx and CO2, the CO2 that forms the photocatalysis of the catalyst present in the
    15 paint, rubber / rubber “TiO2” which, in the reaction with NOx, the substances produced are NO3-, H2O and CO2 ions. PREFERRED EMBODIMENT OF THE INVENTION
    The present invention relates to a composition formed by preferably mineral compounds extracted and selected from igneous rocks with the following mineral composition (Mg / Fe / CaO / TiO2) + SiO2, which are used for the mineralization of CO2 and NOx of the atmosphere, which allows capturing and undoing such harmful gases to reduce the increase in the greenhouse effect and its consequences on health,
    25 converting said gases into a white calcareous powder. These compounds are used and mixed in the manufacture of paints, dyes (for use on facades, airplanes, interiors of homes, etc.) and rubber / rubber materials (for the manufacture of wheels on vehicles also called tires or tires and various rubber or rubber products) mixed all of them in a percentage by weight of
    30 between 0.5% and 15% approximately and with a specific particle diameter of the mineral components between 100 nm to 4000 μm.
    A preferred object of the invention is a mineral mixture for use in paints, either in its manufacture or as a separate component that can be added / mixed in the same paint just before its application. This composition is


    suitable for the mineralization of carbon dioxide and nitrogen oxides comprising the aforementioned mixture of compounds. Its preferred use will be as an additive in paints, lacquers and / or varnishes.
    Another preferred use of the composition of the invention is the manufacture of tires or other rubber and / or rubber elements, preferably of wear. The tires are mainly rubber, they have virtually no porosity, and as they wear out the product is renewed and always acts with toxic gases. In most countries the tire drawing must have a
    10 depth greater than 1.6 mm (European Union) or 2/32 inches (United States), as the thickness of the tire decreases the product or mineral compound of our invention makes the process of carbonation and nitrification, minimizing environmental problems without deteriorate the quality of the tire and practically without increasing the costs of the tires.
    Example 1:
    A study was carried out with different types of paints to observe the absorption / adsorption of our composition:
    20 Various types of materials were used for this experiment, wood, plastic, iron sheet and ready-mixed cement to see the absorption of CO2 emitted by dry ice or carbonic snow. The cement was prepared with ready-mixed Holcim cement. Various types of paint, acrylic and plastic were prepared, both with 5% and 10%
    25 of the igneous rock mineral composition (10% Mg, 6% Fe, 10% CaO, 2% TiO2 and 72% SiO2) with a particle thickness of 800 μm.
    Approximate rectangles of all the materials used between 18 and 21 cm2 were cut. All surfaces were cleaned and left free of dust. All samples were painted two days before the experiment to dry the samples so that they could be weighed at time 0 (T = 0). Weights were recorded in the data collection notebook. All samples were introduced in several glass boxes (a fish tank of 4 L capacity) where carbonic snow was introduced (also heavy - the measurements varied between 29.4 g and 30.5 g) and sealed. Samples were left out of sunlight for 92 h (T = 92) and weighed again after said


    weather.
    From each material, an unpainted sample, a painted sample without composition, a painted sample with 5% composition and another was introduced into the corresponding box
    5 with 10% composition paint. With the cement samples, 29.5 g of dry ice were introduced, with those of wood 30.5 g, with the plastic 29.4 g and with the sheet 30.1 g, everything evaporated at the end of the tests.
    Table 1: Differences in weight of materials exposed to CO2. 10
    Material Block Weight (g)
    0 h 92 hDifference
    Cement only 55.055.40.4
    Painted Cement (A) 44.244.870.67
    Painted Cement (A) 5% 54.756.21.5
    Painted Cement (A) 10% 52.353.931.65
    Wood only 23.523.50.0
    Painted wood (A) 23.423.50.1
    Painted wood (A) 5% 23.424.41.0
    Painted wood (A) 10% 23.424.71.3
    Plastic only 2.52.50.0
    Painted plastic (B) 2.42.40
    Painted plastic (B) 5% 2.43.30.9
    Painted plastic (B) 10% 2.43.61.2
    Sheet only 9.19.10
    Painted plate (B) 9.49.50.1
    Painted plate (B) 5% 9.410.41.0
    Painted plate (B) 10% 9.610.71.1
    The materials in table 1 were painted as follows: Cements and wood with acrylic paint (A), plastic and sheet metal with plastic paint (B). Unpainted materials were introduced in the boxes to see if they had
    15 absorption / adsorption of CO2.
    It has been possible to observe an absorption / adsorption of CO2 with the different materials used, from 0.9 g to 1.65 g. The one that has absorbed the most has been the cement,


    followed by wood and plastic and finally the sheet. Both acrylic and plastic paints have absorbed / adsorbed CO2 and it was observed that on the surfaces where the paints with the formulation had been applied there was a white calcareous powder.
    Example 2:
    In another experiment conducted with water-based paint (used in vehicles) with 5% of the igneous rock mineral composition with (10% Mg, Fe al
    10 6%, 10% CaO, 2% TiO2 and 72% SiO2) with a thickness of 800 μm was used on a sheet metal surface, without lacquer or varnish as a final finish and it was observed that there was CO2 absorption / adsorption by carbonation similar to acrylic and plastic paints.
    15 The same experiment was carried out to see the effectiveness of the lacquer / varnish without adding our compound, using water-based paint with 5% of our compound on the sheet and applying the lacquer / varnish. It was observed that there was no absorption / adsorption of CO2, since the varnish seals it protecting it from environmental elements.
    20 Likewise, we carried out another test with water-based paint (with 5% of our compound), on a sheet metal surface and with lacquer / varnish with 5% of our compound and it was observed that there was absorption / adsorption CO2 by carbonation similar to acrylic and plastic paints.
    25 By performing these types of experiments, it has been possible to demonstrate that using paints or varnishes with virtually no porosity, while the mineral compound with our formulation is present, the product will continue to absorb CO2. 30 Example 3:
    Another experiment performed to observe the absorption / adsorption of nitrogen oxides (NOx) was performed as follows. Plastic, iron sheet and ready-mixed cement were used to see the absorption / adsorption of the submitted NO2. The
    35 samples were painted with 5% plastic paint of the rock mineral composition


    igneous with (10% Mg, 6% Fe, 10% CaO, 2% TiO2 and 72% SiO2) with a particle thickness of 800 μm and allowed to dry.
    The samples were introduced, dried, in fish tanks of 4 liters of capacity and with
    5 20 g of the NO2 gas (Sigma-Aldrich) in the fish tank, the fish tanks were sealed and were exposed to sunlight during the day and artificial light at night for 6 consecutive days.
    After 6 days, the contents of the fish tank were analyzed and it was observed that
    10 there was NO2, as measured by a NO / NO2 / NOx Serinus 40 Gas analyzer. In this experiment there were two chemical processes, the first: the transformation of NOx by the action of TiO2 with light in (ions) NO3 -, H2O and CO2 (photocatalysis) and, on the other hand, the composition of our formulation mineralized the CO2 produced by the reaction of TiO2 with NOx in a thin layer of white powder of calcareous appearance.
    15 It was also observed that there was some moisture due to the production of H2O by TiO2.
    In this way it was verified that the formula completely eliminated NO2 and in turn 20 mineralized, by the carbonation process, the CO2 produced by TiO2.

    权利要求:
    Claims (1)
    [1]
    5 1-Composition for mineralizing carbon dioxide gases and nitrogen oxides comprising a mixture of magnesium (between 1 and 25% by weight), iron (between 1 and 23%), calcium monoxide (between a 1 and 25%), titanium dioxide (between 0.1 and 11%) and silicon dioxide (between 16 and 75%), with a particle diameter between 100 nm and 4000 µm.
    10 2-Use of the composition of claim 1 as an additive in paints, lacquers and / or varnishes.
    3-Use, according to claim 2, of the composition in a weight percentage of between 0.5 and 15%.
    4-Use of the composition of claim 1 as an additive in the manufacture of rubber and / or rubber elements with a weight percentage of between 0.5 and 15%.
    Use of the composition according to claim 4, wherein the rubber and / or rubber elements are wear.
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    同族专利:
    公开号 | 公开日
    WO2018146364A1|2018-08-16|
    EP3581267A1|2019-12-18|
    EP3581267A4|2020-12-16|
    ES2681120B1|2019-09-11|
    US20200001273A1|2020-01-02|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    WO2005082810A1|2004-01-30|2005-09-09|Millennium Chemicals|COMPOSITION FOR USE NOx REMOVING TRANSLUCENT COATING|
    KR20070089261A|2006-02-28|2007-08-31|이종영|The structural materials of the natural mineral and various functional material|
    US20130168228A1|2011-04-12|2013-07-04|Geoffrey A. Ozin|Photoactive Material Comprising Nanoparticles of at Least Two Photoactive Constituents|
    ES1173883Y|2016-12-23|2017-04-05|Asoc De Investig De La Ind Textil |Photocatalytic tile to decontaminate environments|CN111790266A|2020-07-27|2020-10-20|山东大学|System and method for simultaneously removing carbon dioxide and nitrogen oxide|
    法律状态:
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    优先权:
    申请号 | 申请日 | 专利标题
    ES201730156A|ES2681120B1|2017-02-09|2017-02-09|COMPOSITION TO MINERALIZE GASES OF CARBON DIOXIDE AND NITROGEN OXIDE AND USES OF THE SAME|ES201730156A| ES2681120B1|2017-02-09|2017-02-09|COMPOSITION TO MINERALIZE GASES OF CARBON DIOXIDE AND NITROGEN OXIDE AND USES OF THE SAME|
    EP18751536.6A| EP3581267A4|2017-02-09|2018-02-08|Composition for mineralising carbon dioxide and nitrogen oxide gases and uses of same|
    US16/484,309| US20200001273A1|2017-02-09|2018-02-08|Composition for Mineralizing Carbon Dioxide and Nitrogen Oxide Gases and Uses of Same|
    PCT/ES2018/070089| WO2018146364A1|2017-02-09|2018-02-08|Composition for mineralising carbon dioxide and nitrogen oxide gases and uses of same|
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